dc.contributor.author |
Sutherland, Cathleen |
|
dc.contributor.other |
Youngstown State University, degree granting institution. |
|
dc.contributor.other |
Youngstown State University. Department of Chemistry. |
|
dc.date.accessioned |
2020-08-04T20:46:25Z |
|
dc.date.available |
2020-08-04T20:46:25Z |
|
dc.date.issued |
1973 |
|
dc.identifier.other |
907407014 |
|
dc.identifier.other |
b1678833 |
|
dc.identifier.uri |
https://jupiter.ysu.edu/record=b1678833 |
|
dc.identifier.uri |
http://hdl.handle.net/1989/15643 |
|
dc.description |
iv, 50 leaves : illustrations ; 29 cm
Thesis M.S. Youngstown State University 1973.
Includes bibliographical references (leaves 49-50). |
en_US |
dc.description.abstract |
The kinetics of the transesterification reaction between phenyl carbanilate and 1-octanol were studied. The reaction was carried out in 1, 2-dimethoxy ethane as the solvent at a temperature of 100°. Two mechanisms for the transesterification were possible; a two-step
mechanism involving dissociation to isocyanate or a bimolecular displacement involving a carbonyl addition intermediate. The rate constants for both the above mechanisms were calculated from the experimental data. Neither of the above mechanisms alone could
account for the experimental data and a dual mechanism was postulated. |
en_US |
dc.description.sponsorship |
Youngstown State University. Department of Chemistry. |
en_US |
dc.language.iso |
en_US |
en_US |
dc.publisher |
[Youngstown, Ohio] : Youngstown State University, 1973. |
en_US |
dc.relation.ispartofseries |
Master's Theses;no. 0051 |
|
dc.subject |
Transesterification. |
en_US |
dc.subject |
Chemical kinetics. |
en_US |
dc.subject |
Octyl alcohol. |
en_US |
dc.title |
Kinetics of the transesterification reaction between phenyl carbanilate and 1 -octanol |
en_US |
dc.type |
Thesis |
en_US |