Nucleophilic addition of sugar-derived dithiane nucleophiles to sugar lactones : a new approach to c-disaccharides /

McCarthy, Jason Lee.; Youngstown State University. Dept. of Chemistry.

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dc.contributor.author	McCarthy, Jason Lee.	en_US
dc.contributor.author	Youngstown State University. Dept. of Chemistry.	en_US
dc.date.accessioned	2011-01-31T14:16:51Z
dc.date.accessioned	2019-09-08T02:29:58Z
dc.date.available	2011-01-31T14:16:51Z
dc.date.available	2019-09-08T02:29:58Z
dc.date.created	2001	en_US
dc.date.issued	2001	en_US
dc.identifier	50333610	en_US
dc.identifier.other	b18961642	en_US
dc.identifier.uri	http://jupiter.ysu.edu/record=b1896164	en_US
dc.identifier.uri	http://hdl.handle.net/1989/6117
dc.description	ix, 137 leaves : ill. ; 29 cm.	en_US
dc.description	Thesis (M.S.)--Youngstown State University, 2001.	en_US
dc.description	Includes bibliographical references (leaves 64-66).	en_US
dc.description.abstract	Nucleophilic addition of dithiane anions to sugar-derived lactones has been studied as a new route to C-disaccharides. Addition of lithium bis(phenylthio)methane to various furanose lactones yields ketoses, which have been reduced to the parent Cglycosides. Use of a D-ribofuranose-derived dithiane nucleophile in this chemistry leads to a C-disaccharide progenitor, which has been manipulated further to the methylene bridged derivative. The stereochemical course of the addition chemistry, as well as the influence of the sequence of reduction steps will be discussed in detail.	en_US
dc.description.statementofresponsibility	by Jason Lee McCarthy.	en_US
dc.language.iso	en_US	en_US
dc.relation.ispartofseries	Master's Theses no. 0732	en_US
dc.subject.classification	Master's Theses no. 0732	en_US
dc.subject.lcsh	Disaccharides.	en_US
dc.subject.lcsh	Nucleophilic reactions.	en_US
dc.title	Nucleophilic addition of sugar-derived dithiane nucleophiles to sugar lactones : a new approach to c-disaccharides /	en_US
dc.type	Thesis	en_US

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