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Kinetics of the transesterification reaction between phenyl carbanilate and 1 -octanol

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dc.contributor.author Sutherland, Cathleen
dc.contributor.other Youngstown State University, degree granting institution.
dc.contributor.other Youngstown State University. Department of Chemistry.
dc.date.accessioned 2020-08-04T20:46:25Z
dc.date.available 2020-08-04T20:46:25Z
dc.date.issued 1973
dc.identifier.other 907407014
dc.identifier.other b1678833
dc.identifier.uri https://jupiter.ysu.edu/record=b1678833
dc.identifier.uri http://hdl.handle.net/1989/15643
dc.description iv, 50 leaves : illustrations ; 29 cm Thesis M.S. Youngstown State University 1973. Includes bibliographical references (leaves 49-50). en_US
dc.description.abstract The kinetics of the transesterification reaction between phenyl carbanilate and 1-octanol were studied. The reaction was carried out in 1, 2-dimethoxy ethane as the solvent at a temperature of 100°. Two mechanisms for the transesterification were possible; a two-step mechanism involving dissociation to isocyanate or a bimolecular displacement involving a carbonyl addition intermediate. The rate constants for both the above mechanisms were calculated from the experimental data. Neither of the above mechanisms alone could account for the experimental data and a dual mechanism was postulated. en_US
dc.description.sponsorship Youngstown State University. Department of Chemistry. en_US
dc.language.iso en_US en_US
dc.publisher [Youngstown, Ohio] : Youngstown State University, 1973. en_US
dc.relation.ispartofseries Master's Theses;no. 0051
dc.subject Transesterification. en_US
dc.subject Chemical kinetics. en_US
dc.subject Octyl alcohol. en_US
dc.title Kinetics of the transesterification reaction between phenyl carbanilate and 1 -octanol en_US
dc.type Thesis en_US


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