dc.contributor.author |
Malich, Ashley |
en_US |
dc.date.accessioned |
2013-12-16T18:53:02Z |
|
dc.date.accessioned |
2019-09-08T02:36:30Z |
|
dc.date.available |
2013-12-16T18:53:02Z |
|
dc.date.available |
2019-09-08T02:36:30Z |
|
dc.date.issued |
2008 |
|
dc.identifier |
277052295 |
en_US |
dc.identifier.other |
b20382558 |
en_US |
dc.identifier.uri |
http://hdl.handle.net/1989/10789 |
|
dc.description |
x, 162 leaves : ill. ; 29 cm. |
en_US |
dc.description.abstract |
The following work describes the construction and decomposition of azidodeoxy sugars with diazoesters attached. The fate of the projected carbenoid intermediate formed in the presence of a rhodium(II) catalyst resulted in the products of inter- and intramolecular imine formation however, no C-H insertion onto the furanose platform was observed. This research also led to the formation of ketone derivatives and dimeric ethers. |
en_US |
dc.description.statementofresponsibility |
by Ashley Marie Malich. |
en_US |
dc.language.iso |
en_US |
en_US |
dc.relation.ispartofseries |
Master's Theses no. 1122 |
en_US |
dc.subject.lcsh |
Sugars. |
en_US |
dc.subject.lcsh |
Decomposition (Chemistry)--Chemistry, Organic. |
en_US |
dc.subject.lcsh |
Carbohydrates. |
en_US |
dc.title |
Decomposition of Novel Diazosugars: Effects on Regioselectivity |
en_US |
dc.type |
Thesis |
en_US |