Chemistry of acyl nitrenes in the synthesis of carbamates and complex heterocycles

Afeke, Cephas Ofoe

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dc.contributor.author	Afeke, Cephas Ofoe	en_US
dc.date.accessioned	2016-01-08T18:27:13Z
dc.date.accessioned	2019-09-08T02:56:16Z
dc.date.available	2016-01-08T18:27:13Z
dc.date.available	2019-09-08T02:56:16Z
dc.date.issued	2015
dc.identifier	930036133	en_US
dc.identifier.other	b21960057	en_US
dc.identifier.uri	http://hdl.handle.net/1989/11697
dc.description	ix, 167 leaves : illustrations ; 29 cm	en_US
dc.description.abstract	The synthesis of carbamates via Curtius rearrangement utilizing aryl acyl azides together with a wide range of alcohol-containing complex organic molecules was explored through the use of heat. Additionally, the intramolecular insertion of oxycarbonyl nitrenes generated from thermally decomposed azidoformates was studied with several high and low boiling solvents to observe behavior. The insertion of these thermally generated nitrenes into the solvents used may serve as a new way of functionalizing some stable organic compounds and solvents that may originally appear inert in many reaction systems.	en_US
dc.description.statementofresponsibility	by Cephas Ofoe Afeke.	en_US
dc.language.iso	en_US	en_US
dc.relation.ispartofseries	Master's Theses no. 1519	en_US
dc.subject.lcsh	Carbamates.	en_US
dc.subject.lcsh	Heterocyclic compounds.	en_US
dc.subject.lcsh	Chemistry, Organic.	en_US
dc.title	Chemistry of acyl nitrenes in the synthesis of carbamates and complex heterocycles	en_US
dc.type	Thesis	en_US

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